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Conversion of halon 1211 has been studied over γ-Al 2 O 3 and supported 0.5% Pd catalysts (Pd/Al 2 O 3 , Pd/fluorinated Al 2 O 3 , Pd/AlF 3 , Pd/Al 2 O 3 pretreated with CH 4 and CHClF 2 ). The experiments were performed in the temperature range of 443–523K, in a tubular alumina reactor. The temperature of the...
The hydrodehalogenation of halon 1211 over Ni, Pd and Pt supported on γ-alumina was studied. The effect of reaction temperature and hydrogen/halon 1211 input ratio was examined. Steady state catalytic activities of Pd and Pt are very similar, and much higher than that of Ni. Hydrodehalogenation over Pd favours the formation of CH 2 F 2 , while Pt and Ni produce primarily CH 4 ...
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