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This paper tells the recent history of CO2 chemistry through the contributions from members of CIRCC to its birth and growth. Starting with the first transition metal complex bearing CO2 as a ligand synthesized in 1975 by the Aresta Group in Bari, the mode of bonding and the reactivity of coordinated CO2 are discussed. The early applications in chemo‐thermal, electrolytic, and biotechnological processes,...
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