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Homogeneous catalysts prepared from rhodium trichloride in aqueous aromatic amines have been shown to reduce C–Cl bonds under mild water gas shift conditions (T=100°C, PCO=1.0 atm). In a 4-picoline/water solvent mixture, 1,2-dichloroethane is reduced to ethylene and ethane in yields compatible with the consumption of the reducing agent CO and with the formation of CO2. Variation of the catalyst solutions...
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