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Tetra-iso-amyl ammonium bromide (TiAAB), one of the quaternary ammonium salts, was investigated as a semiclathrate former for its potential application in natural gas storage. The dissociation equilibrium temperature of pure TiAAB semiclathrate was the highest at a stoichiometric concentration (3.7mol%) of TiAAB·26.0H2O. The dissociation enthalpy of pure TiAAB (3.7mol%) semiclathrate was 253.0±0.5J/g...
The enclathration of guest gases such as CH4 and CO2 in tetra-n-butyl ammonium chloride (TBAC) semiclathrates and their potential application to natural gas storage and CO2 capture were examined with a primary focus on stability condition measurements and cage filling characteristics. The phase behaviors clearly demonstrated that the double CH4 (or CO2)+TBAC semiclathrates yielded a significantly...
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