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A new linear dithienosilole-based oligothiophene end-capped with methyl and electron-withdrawing dicyanovinyl groups, DTS(Oct)2-(2T-DCV-Me)2, was prepared in good yield. This oligomer exhibited broad absorption spectra in bulk down to the near-IR region with the optical edge at 900nm, resulting in an initially high power conversion efficiency of 5.44% in solution-processed organic solar cells using...
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