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Assembly of 2D materials into hierarchical architectures can produce films with high orientation and special properties. Most research focus on the nano-sized 2D flakes. In this report, zinc hydroxide sulfate (ZHS) large flakes with lateral size up to 410μm were synthesized by hydrothermal treatment of ZnSO 4 ·7H 2 O solution at 150°C. The large ZHS flakes were then used as building...
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