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The weak stability of a hole‐transporter upon approaching the anion state is one of the major bottlenecks for developing long‐life organic light‐emitting devices (OLEDs). Therefore, in this study, we developed a series of thermally and electrically stable hole‐transporters that are end‐capped with four dibenzofuran units. These materials exhibit i) high bond dissociation energy (BDE) toward the anion...
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