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Reaction of titanium(IV) isopropoxide, Ti(OiPr)4, with an equimolar amount of phthalic anhydride resulted in the transfer of an isopropoxido group from the metal atom to one carbonyl group of the anhydride and coordination of the thus formed monoester to the titanium atom. One monoester ligand in Ti2(OiPr)6(μ2‐OOC‐C6H4‐COOiPr)(η1‐OOC‐C6H4‐COOiPr)(iPrOH) is bridging and the other is η1‐coordinated...
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