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Herein we report the colloidal synthesis of Cs3Sb2I9 and Rb3Sb2I9 perovskite nanocrystals, and explore their potential for optoelectronic applications. Different morphologies, such as nanoplatelets and nanorods of Cs3Sb2I9, and spherical Rb3Sb2I9 nanocrystals were prepared. All these samples show band‐edge emissions in the yellow–red region. Exciton many‐body interactions studied by femtosecond transient...
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