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SummaryDehalogenative polycondensation of 1,2-dibromoethylene, trans-1,2-dichloroethylene, and cis-1,2-dichloroethylene with a Ni(0) complex gave a black polymer whose IR spectrum essentially agreed with that of trans-polyacetylene. Suzuki-Miyaura coupling between 1,2-dibromoethylene and vinylene diboronic compounds was applied to synthesis of π-conjugated polymers.
Polyanilines with various degrees of N-grafting have been synthesized by using ring-opening copolymerization of glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane). The obtained polymer has good solubility in common organic solvents. Optical and thermal properties of the N-grafted polyanilines varying with the degree of the N-grafting and length of the graft side chain have been revealed. The polymer...
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