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A new modification of Ba2SnSe5 was synthesized in a flux reaction. The crystal structure of this compound was solved in the space group P121/c1 with cell parameters of a = 21.17189(8) Å, b = 9.0915(3) Å, c = 24.7141(8) Å and β = 125.621(1) °. The compound consists of two slightly different types of Sn4Se1412– as well as Se32– fragments and Ba2+ ions. The structure of the new modification is strongly...
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