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Sandwich-type of luminescent silicotungstates were prepared using the inorganic ligand [SiW 11 O 39 ] 8− (SiW 11 ) coordinating different lanthanide ions (Eu 3+ , Tb 3+ , Dy 3+ ): Eu(SiW 11 ) 2 , Tb(SiW 11 ) 2 and Dy(SiW 11 ) 2 . The potassium salts of these compounds were characterised by several...
The first electrochemical investigation of composites materials based in polyoxometalates (POMs) encapsulated in the porous Metal-Organic Framework (MOF) MIL-101 is reported. The electrochemical behaviour of the porous MIL-101 and composite materials based in two monovacant Keggin-type POMs {K 7 [PW 11 O 39 ]·10H 2 O (PW 11 ) and K 8 [SiW 11 ...
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