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Recently we have shown that HMQC spectra of protonated methyl groups in high molecular weight, highly deuterated proteins have large enhancements in sensitivity and resolution relative to HSQC-generated data sets. These enhancements derive from a TROSY effect in which complete cancellation of intra-methyl 1H-1H and 1H-13C dipolar interactions occurs for 50% of the signal in the case of HMQC, so long...
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