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Erstmals konnte ein zweikerniges metallvermitteltes Basenpaar mit zweiwertigen Metallionen erzeugt werden. Dies gelang durch Kombination des neutralen Purinderivats 1,N6‐Ethenoadenin (ϵA), das als doppelt einzähniger Ligand bevorzugt zwei Metallionen über parallel ausgerichtete N‐M‐Bindungen bindet, mit der kanonischen Nucleobase Thymin (T), die in Gegenwart von HgII deprotoniert wird und so die angehäufte...
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