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α-glucuronidases, components of an ensemble of enzymes central to the recycling of photosynthetic biomass, remove the α-1,2 linked 4-O-methyl glucuronic acid from xylans. The structure of the α-glucuronidase, GlcA67A, from Pseudomonas cellulosa reveals three domains, the central of which is a (β/α) 8 barrel housing the catalytic apparatus. Complexes of the enzyme with the individual reaction...
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