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Front Cover: Unique telechelic‐type polypeptides were synthesized by the facile and environmentally benign enzymatic polymerization using a telechelic initiator. The telechelic polyalanine was found to assemble into long nanofibers by the antiparallel β‐sheet structure whereas the conventional linear polyalanine showed a granule‐like morphology. Further details can be found in the article by Kousuke...
In order to construct unique polypeptide architectures, a novel telechelic‐type initiator with two leucine ethyl ester units is designed for chemoenzymatic polymerization. Glycine or alanine ethyl ester is chemoenzymatically polymerized using papain in the presence of the initiator, and the propagation occurs at each leucine ethyl ester unit to produce the telechelic polypeptide. The formation of...
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