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The carbon dioxide (CO2) cycloaddition of epoxides to cyclic carbonates is of great industrial importance owing to the high economical values of its products. Single‐atom catalysts (SACs) have great potential in CO2 cycloaddition by virtue of their high atom utilization efficiency and desired activity, but they generally suffer from poor reaction stability and catalytic activity arising from the weak...
The spontaneous reaction between Zn and H2O is of critical importance and could plausibly be used to produce H2 gas, especially under neutral conditions. However, this reaction has long been overlooked owing to its sluggish kinetics and Zn consumption. Herein, a unique self‐co‐electrolysis system (SCES) is reported, which uses a Zn anode, a CoP‐based catalytic cathode, and a neutral phosphate buffer...
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