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Immobilized Candida antarctica lipase B has been shown to form the pharmaceutically important (S)-γ-fluoroleucine ethyl ester intermediate from the ring opening of an azlactone with ethanol, providing 79% yield and 78% enantiomeric excess (ee) for a stirred tank batch process demonstrated at multi kilogram scale. A kinetic analysis of the reaction system was defined which included the selective enzyme...
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