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Nanosecond flash photolysis studies have been carried out on the tetrameric clusters Cu 4 I 4 L 4 (L = pyridine (py), 4-t-butyl pyridine (4-Bu t -py)), 4-phenyl pyridine (Phpy) or piperidine (pip)). A broad transient absorption band in the visible region was observed for each of the clusters with aromatic heterocycle ligands upon excitation at 337 or 355 nm but no...
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