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Charcoal supported metal salt catalysts showed activities for the lignin gasification at 673 K, especially the catalysts without chloride anion showed the complete gasification. The order of activity for the gasification among the metal species was following: ruthenium > rhodium > platinum > palladium ~ nickel. X-ray absorption fine structure analysis revealed that small metal particles were...
Lignin gasification in supercritical water over charcoal supported ruthenium trivalent salts was studied using a batch reactor at 673 K. Ruthenium (III) nitrosyl nitrate on charcoal (Ru(NO)(NO3)3/C) was more active than ruthenium (III) chloride on charcoal (RuCl3/C) for the gasification reaction. EXAFS analysis revealed that ruthenium metal particles were formed in both RuCl3/C and Ru(NO)(NO3)3/C...
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