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Activities of graphite-supported rhodium catalysts were examined for the hydrogenation of naphthalene in supercritical carbon dioxide (scCO 2 ) solvent at 313K, and results were compared with those of activated carbon-supported rhodium catalysts. The graphite-supported rhodium catalysts exhibited higher activities on a catalyst-weight basis and higher turnover frequency values for the naphthalene...
Catalytic hydrogenation of naphthalene to decalin was studied over a carbon-supported rhodium catalyst in supercritical carbon dioxide solvent at 333 K, and the results were compared with those in an organic solvent. cis-, trans-Decalin and tetralin were formed from the beginning of the reaction in supercritical carbon dioxide. Higher concentration of hydrogen in carbon dioxide solvent and on the...
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