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The anionic FeIII complex exhibiting cooperative spin transition with a wide thermal hysteresis near room temperature, K[Fe(5‐Brthsa)2] (5‐Brthsa‐H2=5‐bromosalicylaldehyde thiosemicarbazone), is reported. The hysteresis (Δ=69 K in the first cycle) shows a one‐step transition in heating mode and a two‐step transition in cooling mode. X‐ray structure analysis showed that the coexistence of hydrogen...
Spin Crossover S. Kang, O. Sato et al. report a novel approach for introducing cooperativity by intermolecular interactions into spin‐crossover complexes so that they can exhibit a cooperative spin transition with a large thermal hysteresis loop at room temperature. The introduction of alkali‐metal coordination bonds and cation–π interactions into spin‐crossover metal centers gives rise to strong...
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