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Neutral five‐atomic cumulenes formally consisting of two pseudohalogens (e.g., NCO, NNN, NSO) by sharing the central nitrogen atom are exotic species that have been barely studied. Through flash vacuum pyrolysis of CF3S(O)NCO at ca. 1200 K, sulfinyl isocyanate, bearing resonance structures of O=C−N=S=O and O=C=N−S=O, has been generated in the gas phase and subsequently characterized in cryogenic matrices...
Ein flüchtiges exotisches Heterocumulenradikal, OCNSO, wird in der Gasphase bei ca. 1200 K erzeugt und geht bei Bestrahlung oder Temperung in kryogenen Matrices (2.8–15.0 K) eine gegenseitige Umwandlung zwischen den syn‐ und anti‐Konformeren ein. Wie G. Frenking, J. S. Francisco, X. Q. Zeng et al. in ihrer Zuschrift auf S. 2172 ff. zeigen, können neutrale Spezies, die formal aus zwei Pseudohalogenen...
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