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Der Rotlicht‐induzierte Abbau des α‐Hydroxymethylperoxy‐Radikals in der Gasphase wurde mittels quantenchemischer Rechnungen untersucht. In ihrer Zuschrift auf S. 15937 ff. berichten J. S. Francisco und M. Kumar über die wichtige Rolle des H2O⋅HO2‐Radikalkomplexes, der in erheblichem Überfluss in der Troposphäre existiert. Die Reaktion von organischen Peroxyradikalen mit dem HO2‐Radikal und dem H2O⋅HO...
The gas‐phase decomposition of the α‐hydroxy methylperoxy radical has been theoretically examined, and the results provide insight into a new source of the hydroperoxy radical (HO2) in the troposphere. Bimolecular peroxy decomposition is promoted by the red‐light or near‐IR radiation excitation. The calculations suggest for the first time, an important chemical role for the H2O⋅HO2 radical complex...
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