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Recent developments in the use of N-heterocyclic carbenes (NHC) as ligands in palladium-mediated transformations are described. These versatile ligands afford steric and electronic control of the metal environment, just as tertiary phosphines, yet they also allow synthetic access and operational catalytic advantages compared to metal–tertiary phosphine-centered transformations.
N-heterocyclic carbenes (NHCs) have attracted increasing attention since their discovery. Notably, they have allowed for major advances in palladium-catalyzed reactions. Mainly known for their application in cross-coupling reactions, this review intends to provide a broader overview of (NHC)-palladium systems in organic transformations.
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