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In this work, we report a transition‐metal free approach for the construction of primary aromatic amines from aryl boronic acids and esters with N‐Boc‐O‐tosylhydroxylamine as an amine surrogate. Bench stable TsONHBoc is easy to use and it produces a non‐interfering water‐soluble by‐product. The protocol is operative for both electron‐rich and electron‐deficient aryl boronic acids under acidic conditions,...
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