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This paper focused on study of the interfacial consecutive electron transfer (ET) kinetics and the redox behaviors of three 5,10,15,20-zinc-tetraarylporphyrins (ZnTArPs) with a systematic variation of meso-π-extension at a 2n (0≤n≤2) pattern, where 2n was the number of benzene ring in an aryl group. The two-step redox potentials of 5,10,15,20-zinc-tetraphenylporphyrin (ZnTPP) were more negative than...
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