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Natural rubber (NR)-based hollow latex (HL) particles have been prepared by seeded emulsion polymerization of methyl methacrylate/divinyl benzene/acrylic acid (MMA/DVB/AA) monomers on NR seed. By using tert-butyl hydroperoxide/tetraethylene pentamine (t-BuHP/TEPA) as a redox initiator, the locus of polymerization was localized at the surface of the NR particle. After swelling with monomers, DVB in...
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