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Moment equations were developed on the basis of the Einstein equation for diffusion and the random walk model to analytically determine the rate constant for the interfacial solute permeation from a bulk solvent into molecular aggregates (kin) and the inverse rate constant from the molecular aggregates to the bulk solvent (kout). The moment equations were in good agreement with those derived in a...
Moment equations were developed on the basis of the principle of relativity for analyzing elution peak profiles measured by ACE to analytically determine the association (ka) and dissociation (kd) rate constants of intermolecular interactions. Basic equations representing the mass balance, mass transfer rate, and reaction kinetics in ACE system in a Galilean coordinate system S were transformed to...
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