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The unusual electrochemical behavior of sodium (6,8-diferrocenylmethylthio)octanoate in aqueous solutions is reported. This diferrocene derivative forms an anion, gives a two-electron oxidation voltammetric wave and, correspondingly, changes its charge from −1 to +1. The electrode reaction belongs to the class of sign-reversal processes for which the theory predicts a very high ratio of the faradaic...
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