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The synthesis of three random copolymers—BD2FON‐OB30, BD2FON‐OB50, and BD2FON‐OB70—comprised of different molar ratios of alkoxyphenylene and alkoxynaphthalene is reported by adjusting the ratio of these units for optimized energy levels. When organic photovoltaics are fabricated using these polymers as the electron donor, introduction of the binary solvent additive dramatically enhances power conversion...
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