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The electrodeposition of Cu on n-type single-crystal GaN(0001) electrode from sulfate solution was investigated by electrochemical techniques and scanning electron microscopy. It was found that Cu deposition on GaN(0001) commenced at a large negative potential of −840mV vs. Pt/Pt 2+ and was quasi-reversible and mass transfer limited. On the basis of Tafel plot, a low exchange current density...
The mixing behavior of viscosities of electrolyte solutions under isopiestic equilibrium has been studied for the first time using the Eyring's absolute rate theory and the semi-ideal hydration model. The concentration dependence of the change in molar free energy of activation for flow has been formulated and discussed based on the concept of average hydration number and the structure-making or structure-breaking...
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