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Two new cyanido-bridged coinage metal compounds are presented. A novel hetero trinuclear Ag–Cu–Au compound of formula [AgCuAu(CN)3(PPh3)5](H2O)2 1 is described with bridging cyanide ligands between the metals, and terminal phosphane ligands for Cu(I) and Ag(I). Silver is tetrahedrally coordinated by 3 phosphane ligands and a bridging cyanido ligand, copper is coordinated tetrahedrally by 2 phosphanes,...
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