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A photo-transformation of NO2 into NO at the N2 presence is discovered over a WO3 photocatalyst under UV/visible light irradiation. During the photoreaction, we found that both NO2 and N2 disappear and additional NO appears at the same time. A reaction pathway is proposed and verified by the results of an online chemiluminesce NOx analyzer, GC-TCD, and in situ DRIFT monitoring of the reactants and...
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