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The valence-shell electronic structure of trans-dichloroethylene has been investigated by symmetric noncoplanar (e, 2e) spectroscopy. Ionization energy (IE) spectra of the valence shell (6-46 eV) have been obtained at relative azimuthal angles of 0° and 8° and compared with literature photoelectron (PE) data. The present work confirms the presence of extensive many-body features in the inner-valence...