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We report on two regioisomeric, diazocine ligands 1 and 2 that can both be photoswitched between the E‐ and Z‐configurations with violet and green light. The self‐assembly of the four species (1‐Z, 1‐E, 2‐Z, 2‐E) with CoII ions was investigated upon changing the coordination vectors as a function of the ligand configuration (E vs Z) and regioisomer (1 vs 2). With 1‐Z, Co2(1‐Z)3 was self‐assembled,...
Wir berichten über zwei regioisomere Diazocinliganden 1 und 2, die beide mit violettem und grünem Licht zwischen den E‐ und Z‐Konfigurationen geschaltet werden können. Die Selbstorganisation der vier Spezies (1‐Z, 1‐E, 2‐Z, 2‐E) mit CoII‐Ionen wurde nach Änderung der Koordinationsvektoren in Abhängigkeit von der Ligandenkonfiguration (E vs. Z) und dem Regioisomer (1 vs. 2) untersucht. Mit 1‐Z bildet...
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