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Rate constants are reported for the vibrational deactivation of the asymmetric stretching and bending modes of CO 2 . A large number of collision partners has been studied and the results span the temperature range 300 to 140 K. The measurements were made using the laser induced fluorescence technique. CO 2 was pumped directly to the CO 2 (00 0 1) level by an HBr...
Rate constants are reported for the vibrational deactivation of the bending modes of CD 4 and CH 4 in the temperature range 295 to 90 K for the former and 295 to 140 K for the latter. A large number of collision partners was investigated with twelve systems being studied for CD 4 relaxation and six for CH 4 . These experiments used the laser induced fluorescence technique...