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The relationship between Cd and phosphate is intriguing for unravelling geochemical cycling in the modern ocean. Moreover it is relevant for reconstructing Cd or phosphate distributions in paleoceanography. Whether the global Cd/phosphate data indicate a single linear relationship or whether the data are better described by two different linear relationships, one for the North Atlantic Ocean data...
This review draws together the structural information presently available for almost 40 organocadmium and carbonyl derivatives. The cadmium oxidation state varies from 0 to +2. There is only one example of Cd(I), which is in a distorted tetrahedral environment. The oxidation state of +2 is most abundant, with Cd(II) found in digonal, trigonal planar, tetrahedral and five-coordinate (mostly trigonal-pyramidal)...
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