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Non‐aqueous solvents, in particular N,N‐dimethylaniline (NMP), are widely applied for electrode fabrication since most sodium layered oxide cathode materials are readily damaged by water molecules. However, the expensive price and poisonousness of NMP unquestionably increase the cost of preparation and post‐processing. Therefore, developing an intrinsically stable cathode material that can implement...
Layered manganese‐based oxides (LMOs) are promising cathode materials for sodium‐ion batteries (SIBs) due to their versatile structures. However, the Jahn–Teller effect of Mn3+ induces severe distortion of MnO6 octahedra, and the resultant low symmetry is responsible for the gliding of MnO2 layers and then inferior multiple‐phase transitions upon Na+ extraction/insertion. Here, hexagonal P2‐Na0.643...
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