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Catalytic properties of Fe-MIL-101 and Cr-MIL-101 metal–organic frameworks in the solvent-free oxidation of cyclohexene and α-pinene with molecular oxygen have been explored. Both catalysts allow alkene oxidation under mild conditions (1bar O 2 , 40–60°C) and afford allylic oxidation products. The nature of catalysis and the product distribution strongly depend on the nature of the transition...
Cu-MOF [Cu(bpy)(H 2 O) 2 (BF 4 ) 2 (bpy)] (bpy: 4,4′-bipyridine) shows promising catalytic activity and high selectivity in allylic oxidation of cyclohexene with molecular oxygen as the only oxidant. Under close to ambient conditions and in the absence of solvent the selectivity in cyclohexene hydroperoxide reached 90%. The combined catalytic, spectroscopic, thermogravimetric,...
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