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Different TAPO-5 materials, prepared from Ti(III) chloride, have been tested as catalysts in the oxidation of cyclohexene with hydrogen peroxide under anhydrous conditions. Solid TiCl 3 was shown to render better synthesis reproducibility and higher catalytic activity of the resultant materials compared to TiCl 3 aqueous solution. The synthesis of these materials was carried out under...
Allylic oxidation of cyclohexene was carried out over a Schiff base copper complex and its immobilized analogue supported on organically modified silica. The immobilized complex has been characterized by using atomic absorption spectrophotometry (AAS), FT-IR, EPR and UV–vis spectroscopic studies and SEM image analysis. The catalytic oxidation of cyclohexene was carried out over this copper complex...
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