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Vanadate complexes of α-hydroxycarboxylic acids form readily and reversibly in aqueous solution. 2-Methyl-2-hydroxypropanoic acid (α-hydroxyisobutyric acid) provides a convenient system to demonstrate the utilization of 51 V-NMR spectroscopy in the study of the formation of various products and to provide examples of procedures used to determine product stoichiometries and equilibrium...
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