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Eastman Chemical Company first initiated its Chemicals from Coal program in the mid-1970s. The program led to the successful commercialization of a process to produce acetic anhydride entirely from coal-based synthesis gas in 1983. However, Eastman Chemical Company did not stop to work with on chemicals from coal with the attainment of the acetic anhydride process and they continued to look at the...
[Cp * Rh(CO) 2 ] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 moldm 3 h -1 in the absence of hydrogen; [Cp * RhI 2 (CO)] which forms from it is also catalytically active giving rates of 1.2 moldm 3 h -1 under the same conditions.
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