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The electronic structure of the ternary YNi_4B compound, crystallizing in the hexagonal CeCo_4B structure (P6/ mmm space group), was studied by X-ray photoelectron spectroscopy and ab initio calculations. Core levels and the valence band were investigated. The X-ray photoelectron spectroscopy valence band is compared with that obtained from ab initio calculations. The valence band spectrum at the...
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