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Forming functional blood vessel networks in engineered or ischemic tissues is a significant scientific and clinical hurdle. Poly(ethylene glycol) (PEG)‐based hydrogels are adapted to investigate the role of mechanical properties and proteolytic susceptibility on vascularization. Four arm PEG vinyl sulfone is polymerized by Michael‐type addition with cysteine groups on a slowly degraded matrix metalloprotease...
Poly(dimethylsiloxane) can be covalently coated with ultrathin NCO‐sP(EO‐stat‐PO) hydrogel layers which permit covalent binding of cell adhesive moieties, while minimizing unspecific cell adhesion on non‐functionalized areas. We applied long term uniaxial cyclic tensile strain (CTS) and revealed (a) the preservation of protein and cell‐repellent properties of the NCO‐sP(EO‐stat‐PO) coating and (b)...
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