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In this paper, we demonstrate, using both experiment and simulation, how sample zone conductivity can affect plug–plug mixing in small molecule applications of electrophoretically mediated microanalysis (EMMA). The effectiveness of in‐line mixing, which is driven by potential, can vary widely with experimental conditions. Using two small molecule systems, the effects of local conductivity differences...
The aim of this work was to clarify the mechanism taking place in field‐enhanced sample injection coupled to sweeping and micellar EKC (FESI‐Sweep‐MEKC), with the utilization of two acidic high‐conductivity buffers (HCBs), phosphoric acid or sodium phosphate buffer, in view of maximizing sensitivity enhancements. Using cationic model compounds in acidic media, a chemometric approach and simulations...
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