The cover picture shows a snapshot of the landscape of Ninghai in the east coast of China. The cross‐coupling reaction of a trisubstituted alkenyl bromide with a trisubstituted alkenyl boronate proceeds smoothly with a Pd(OAc)2–Aphos‐Y catalyst system under conditions (35 °C, THF/H2O, K3PO4�3H2O) similar to the natural surrounding environment. The hemilabile Aphos‐Y ligand is known to form P,O‐chelating and P‐monodentate complexes with palladium(0) and palladium(II) species, which facilitate various steps in the catalytic cycle. The mild coupling conditions, without the use of a highly toxic TlI base, renders the Pd(OAc)2–Aphos‐Y catalyst system promising for polyene natural product total synthesis. Details are discussed in the article by Y. Wang and W.‐M. Dai on p. 323 ff.