Salts containing metal phthalocyanine and fullerene anions: {cryptand[2.2.2](Na+)}1.5{CoI(Pc2–)}–0.5(C60·–)·2C6H4Cl2 (1) and {cryptand[2.2.2](Na+)}2{VIVO(Pc·3–)}–(C60–)·C6H4Cl2 (2) were obtained. The {CoI(Pc2–)}–anions are formed by metal centered reduction whereas the Pc2– macrocycles are reduced at the formation of {VIVO(Pc·3–)}–. Fullerenes form zigzag chains in 1 in which they are positionally disordered showing different degree of dimerization [loose packed or π‐stacked pairs from the monomers and singly bonded (C60–)2 dimers]. Singly bonded (C60–)2 dimers in 2 also coexist with pairs of π‐stacked C60·–monomers. The (MPc)– anions are isolated in the salts alternating with the {cryptand(Na+)} cations. Magnetic measurements by EPR technique show the presence of spins in 1 both on C60·–(S = 1/2) and the CoI atoms having S = 1 spin state. These spins are weakly antiferromagnetically coupled in the fullerene chains (Θ = –6 K) but show nearly paramagnetic behaviour for isolated {CoI(Pc2–)}– anions. Both S = 1/2 spins in 2 are mainly localized on VIV and delocalized over Pc·3– since only about 10 % of C60·– from total amount of fullerene is preserved. Spins in 2 show only weak antiferromagnetic coupling with Θ = –2 K within one {VIVO(Pc·3–)}– unit.