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The development of efficient electrocatalysts with non‐copper metal sites for electrochemical CO2 reduction reactions (eCO2RR) to hydrocarbons and oxygenates is highly desirable, but still a great challenge. Herein, a stable metal–organic framework (DMA)4[Sn2(THO)2] (Sn‐THO, THO6− = triphenylene‐2,3,6,7,10,11‐hexakis(olate), DMA = dimethylammonium) with isolated and distorted octahedral SnO62− active...
A non‐copper metal based catalyst for the deep electroreduction of CO2 to hydrocarbons is reported by Pei‐Qin Liao and co‐workers in their Communication (e202301767). For the first time, a Sn‐based catalyst was developed for the electrochemical CO2 reduction reaction (eCO2RR) to produce hydrocarbons. This Sn‐based MOF shows an unexpected performance in the eCO2RR to produce CH4, as formate or CO are...
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