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Die π‐π‐Wechselwirkungen zwischen diskreten kofacial orientierten Naphthalindiimid‐Einheiten (NDI) in Cyclo‐NDI wurden durch Änderungen der Temperatur und der Lösungsmittelpolarität moduliert. Wie M. Takeuchi et al. in ihrer Zuschrift auf S. 5292 berichten, führte die Abstimmung der elektronischen Kommunikation durch den Raum durch die konformative Umwandlung zwischen monomer‐ und dimerartigen Merkmalen...
The design and synthesis of an enantiomeric pair of 1,8‐diethynylanthracene‐bridged naphthalenediimide (NDI)‐based cyclophanes (Cyclo‐NDIs) are reported. Each enantiomer of Cyclo‐NDI exhibits a circularly polarized luminescence signal with a relatively large luminescence dissymmetry factor (glum=±8×10−3). We have further investigated the modulation of through‐space electronic communication between...
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